Di-μ-oxido-bis[(4-formyl-2-methoxyphenolato-κO1)oxido(1,10-phenanthroline-κ2N,N′)vanadium(V)]
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منابع مشابه
Di-μ-oxido-bis[(4-formyl-2-methoxyphenolato-κO 1)oxido(1,10-phenanthroline-κ2 N,N′)vanadium(V)]
The title complex, [V(2)(C(8)H(7)O(3))(2)O(4)(C(12)H(8)N(2))(2)], is a centrosymmetric dimer formed by two V(V) complex units bridged by two μ(2)-oxido groups. The V(V) atom is six-coordinated by three oxide O atoms, one O atom from a vanillinate ligand and two N atoms from a 1,10-phenanthroline ligand in a significantly distorted octa-hedral geometry. In the crystal structure, weak inter-molec...
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In the title coordination polymer, {[Na(2)(C(8)H(7)O(3))(H(2)O)(4)](C(8)H(7)O(3))}(n), all the non-H atoms except the water O atoms lie on a crystallographic mirror plane. One sodium cation is bonded to four water O atoms and one vanillinate O atom in a distorted square-based pyramidal arrangement; the other Na(+) ion is six-coordinated by four water O atoms and two vanillinate O atoms in an ir...
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The title salt, (C(5)H(6)N)(4)[Mo(2)Cl(2)O(5)(SO(4))(2)], comprises four pyridinium cations for each [(MoClO(2))(2)(μ-O)(μ-SO(4))(2)](4-) anionic unit. The asymmetric unit consists of three aggregates of the empirical formula. The tetra-anionic bimetallic molybdenum(VI) cluster is unprecedented and contains two sulfate and one oxide bridges. This structure constitutes the first example of a non...
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The title compound, [Sb(2)(C(6)H(5))(6)(CH(3)O)(2)O]·2CH(3)OH, is the methanol disolvate of a dinuclear triphenyl-anti-mony derivative. The mol-ecule shows C(s) symmetry. The Sb-O-Sb angles cover a range from 89.65 (10)° to 102.08 (13)°. In the crystal structure, two O-H⋯O hydrogen bonds are present.
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In the title salt, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O], the ionic components are linked into a two-dimensional supra-molecular layer by two pairs of C-H⋯Cl hydrogen bonds and π-π stacking inter-actions [centroid-centroid distances = 3.655 (4) and 3.498 (3) Å]. The salt is characterized as a mixed-valent Fe(II)-Fe(III) compound, in which an Fe(II) atom is coordinated by three phen ligands, formi...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809032516